编号:FTJS09605
篇名:g-C3N4/过渡金属硫化物复合材料的结构设计、合成及光催化应用
作者:唐飞 蔡文宇 陈飞 朱晨 刘成宝 陈志刚
关键词: 催化材料 光催化 光化学 纳米材料 g-C3N4 过渡金属硫化物
机构: 苏州科技大学江苏省环境功能材料重点实验室 苏州科技大学材料科学与工程学院 苏州科技大学江苏水处理技术与材料协同创新中心
摘要: Graphite carbonnitride(g-C3N4),as an inorganic non-metallic semiconductor photocatalytic material,comprises a special energy band and crystal structure,which receives extensive attention in environmental governance and clean energy.However,the single-phase g-C3N4 has disadvantages of small response range to natural light,small specific surface area,few reactive sites,and high recombine efficiency of photoelectron-hole pairs,which limit its large-scale utilization in the field of photocatalysis.Transition metal sulfides have a special energy band structure,and excellent physical and photocatalytic properties,which show great development potential in photocatalytic applications.There were numerous researches generally focused on the construction of heterojunctions to solve the problems that catalytic materials has,such as narrow optical response range,low photocatalytic quantum efficiency due to the easy combination of carriers,short duration of carriers and insufficient reactive sites.Herein,the performance,structure design and reaction mechanism of the g-C3N4/transition metal sulfide photocatalytic materials were reviewed,the progress of the heterogeneous junction construction was discussed,and the development prospect of the g-C3N4/transition metal sulfide composite materials was prospected.